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Friday, 30 June 2017

New solar-powered catalyst produces methane from CO2

ADELAIDE, AUSTRALIA: Australian scientists have paved the way for carbon neutral fuel with the development of a new efficient catalyst that converts carbon dioxide(CO2) from the air into synthetic natural gas in a ‘clean’ process using solar energy.
Undertaken by the University of Adelaide in collaboration with CSIRO, the research could make viable a process that has enormous potential to replace fossil fuels and continue to use existing carbon-based fuel technologies without increasing atmospheric CO2.
The catalyst the researchers have developed effectively drives the process of combining CO2 with hydrogen to produce methane (the main component of the fossil fuel natural gas) and water. Currently, natural gas is one of the main fuels used for industrial activities.
“Capturing carbon from the air and utilising it for industrial processes is one strategy for controlling CO2 emissions and reducing the need for fossil fuels,” said University of Adelaide PhD candidate Renata Lippi, first author of the research.
The research is published online the Journal of Materials Chemistry A.
“But for this to be economically viable, we need an energy efficient process that utilises CO2 as a carbon source. Research has shown that the hydrogen can be produced efficiently with solar energy. But combining the hydrogen with CO2 to produce methane is a safer option than using hydrogen directly as an energy source and allows the use of existing natural gas infrastructure.
“The main sticking point, however, is the catalyst – a compound needed to drive the reaction because CO2 is usually a very inert or unreactive chemical.”
The catalyst was synthesised using porous crystals called metal-organic frameworks which allow precise spatial control of the chemical elements.
“The catalyst discovery process involved the synthesis and screening of more than one hundred materials. With the help of CSIRO’s rapid catalyst testing facility we were able to test all of them quickly allowing the discovery to be made in a much shorter period of time,” said Dr Danielle Kennedy, AIM future science platform director with CSIRO. “We hope to continue collaborating with the University of Adelaide to allow renewable energy and hydrogen to be applied to chemical manufacturing by Australian industry.”
With other catalysts, there have been issues around poor CO2 conversion, unwanted carbon monoxide production, catalyst stability, low methane production rates and high reaction temperatures.
This new catalyst efficiently produces almost pure methane from CO2. Carbon monoxide production has been minimised and stability is high under both continuous reaction for several days and after shutdown and exposure to air. Importantly, only a small amount of the catalyst is needed for the high production of methane which increases economic viability. The catalyst also operates at mild temperatures and low pressures, making solar thermal energy possible.
“What we’ve produced is a highly active, highly selective (producing almost pure methane without side products) and stable catalyst that will run on solar energy,” said project leader professor Christian Doonan, director of the University’s Centre for Advanced Nanomaterials. “This makes carbon-neutral fuel from CO2 a viable option.”
© University of Adelaide News
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Covestro presents new film solutions for security documents

LEVERKUSEN, GERMANY: Covestro AG said that it will present new and hi-tech products for ID cards, with films that improve security and enable efficient production of cards.
To meet the many different demands of card manufacturers, Covestro has developed a range of polycarbonate films under the Makrofol and Bayfol brands and the Platilon ID range of thermoplastic polyurethane (TPU) films.
Durable ID
“Multi-layer TPU films and combinations with polycarbonate films for applications where excellent mechanical strength and durability are crucial are new to our portfolio,” said Georgios Tziovaras, applications engineer in special films at Covestro.
One example is the thin fold of passports, which consists of a Platilon ID composite film and is laminated inside onto the data page. The production process is highly efficient and the composite is also long-lasting. Documents can be opened and closed again any number of times without affecting flexibility or tearing at the fold.
As the TPU films soften at temperatures similar to or higher than corresponding polycarbonate Makrofol ID products from which the data pages are made, they cannot be separated from each other again without damage being caused. “As a result, they can’t be used to manufacture new ID cards and thus offer excellent anti-forgery protection,” added Tziovaras.
Further security features can be integrated
On request, Platilon ID products can also be equipped with laser-reactive properties to integrate further security features into the fold. As with the polycarbonate data pages, it can also be personalised using standard laser engraving equipment.
The thickness of the layers in the composite films, which is thinner than for individual films, also enables greater design freedom. The data page can thus also be made thinner, while nonetheless offering high strength and flexibility. This simplifies the integration of security features, and the thinner data page also saves money.
Contrast-rich and secure personalization
In ID documents made using this product, the holder’s data and photo can be laser-engraved in higher contrast than is possible for standard laser-reactive overlay films. The data are also integrated into the core, with the result that the film also offers enhanced anti-forgery protection.
Personalization is faster and more cost-effective than the conventional production. The development of this film and the patent-protected Superlaser technology is Covestro’s response to the latest trends on the security document market.
Ultra-thin film makes chip invisible
Other innovations include extremely thin white polycarbonate films in the Makrofol ID range. With their high opacity, they ensure the underlying chip cannot be seen following lamination. The thin layer of just 30/50 micrometres also offers more freedom to incorporate additional layers in the card.
© Chemical Today News
Read More: Covestro presents new film solutions for security documents

Merck establishes new foundation for global healthcare solutions

DARMSTADT, GERMANY: Merck Group announced the establishment of the Merck Foundation, a non-profit limited liability company. Through this foundation, Merck combines many of its corporate responsibility activities under one roof and considerably expands its scope to address health, social and economic challenges of the 21st century.
“The vision of the new foundation is the world where everyone can lead a healthy and fulfilling life, also those living under disadvantaged conditions,” said Frank Stangenberg-Haverkamp, chairman of the board of trustees of the new foundation.
“With the Merck Foundation, we will continue our commitment towards improving access to innovative healthcare solutions in underserved communities, building healthcare and scientific research capacity and advancing people’s lives through science and technology,” added Haverkamp.
“The Merck Foundation will focus on initiatives that will contribute towards the sustainable development goals outlined by the United Nations. To achieve the foundations’ goals, we will develop and implement coherent strategies, result oriented programs and initiatives, provide grants to support projects and help raise funds where needed,” said Rasha Kelej, who has been appointed CEO of the Merck Foundation.
Kelej (45) joined Merck in 1996, working exclusively in positions relevant to corporate responsibility and market development with a strong focus on Africa and developing countries.
© Chemical Today News 
Read More: Merck establishes new foundation for global healthcare solutions

FMC to sell its Omega-3 business to Pelagia

PHILADELPHIA, US: FMC Corporation (FMC) has signed a definitive agreement to sell its Epax Omega-3 business to Pelagia AS, a leading producer of pelagic fish products.
The deal is expected to close by the end of Q3 2017.
"We are pleased to sell our Omega-3 business to Pelagia. We believe Pelagia provides a strong strategic fit for our Epax Omega-3 product line and will complement Pelagia's existing portfolio,” said Eric Norris, president, FMC health and nutrition.


Read More: FMC to sell its Omega-3 business to Pelagia

Hikma makes organisational changes in US, CEO to retire

LONDON, UK: Hikma Pharmaceuticals PLC (Hikma) announced the organisational changes to its US business (West Ward Pharmaceuticals) to reflect its enhanced US market positioning and to better align with the global Hikma organisation.
Main changes include the following:
  • Michael Raya, CEO of the US business will retire at the end of this year. Raya has led the US business for more than 25 years and in that time, has demonstrated strong leadership that has enabled Hikma to grow into a top 10 generics company in the US.
  • From 1 July, the US business will be organised into two entities both of which will report to the chairman and CEO, Said Darwazah. There will be a US generics division and a US injectables division.
  • Brian Hoffmann has been promoted to President of the US Generics Division.  Mr Hoffmann brings a wealth of experience in strategy, business development, M&A and marketing.  Since joining West-Ward/Hikma in 2009, he has been instrumental in the growth of the US business.
  • Riad Mishlawi has been promoted to the role of CEO, injectables division, responsible for all injectable operations globally, including the newly formed US Injectables Division. Riad brings both breadth and depth to this role, having worked with the company since 1990 and led the injectables division through a period of rapid growth.
  • Raya will continue to have oversight of the US business, working closely with the team for the rest of the year to transition the business.
“I would like to thank Mike for his many years of successful leadership of our US business and wish him well in his retirement. The leadership and organisational changes we have announced today will bring greater organisational focus and alignment, establish a scalable structure to enable continued growth, and strengthen the US leadership team,” said Said Darwazah, chairman and CEO of Hikma.
“Together with my colleagues, I am proud of what we were able to accomplish during my time at Hikma/West Ward and leave confident that the company is extremely well-positioned for the future,” said Raya, commenting on his retirement.
© Worldofchemicals News 
Read More: Hikma makes organisational changes in US, CEO to retire

Foam innovations addressing global challenges

By Frank de Vries
The growth in the world’s population is posing increasing challenges along the food supply chain, on precious resources, housing and on transportation. Among these challenges, two principal needs can be distinguished: those for improvements in sustainability and in efficiency.
SABIC regards polymer foam technologies as essential to meet these improvement needs: on the one hand they offer material and energy savings while retaining or even improving product performance, and on the other hand, they offer unique benefits over non-foamed polymer technologies, such as thermal and acoustic insulation, cushioning and protection. Enhanced physical properties and improved foamability of the polymers themselves provide the key to enabling more efficient material usage and energy saving with foam technologies.
A large, diverse and growing industry
The polymer foam-producing industry currently consumes around 25 million metric tonnes of plastics every year, creating revenues of around $83 billion. It is expected to grow by close to 2.5% per year over the next ten years. Polymer foams are widely used in numerous industries, most important among them being building & construction (25% of the total market), packaging (24%), furniture (19%) and individual and mass transportation (13%).
In the building & construction segment, there is a clear need for low-cost, energy-efficient houses that can be built quickly. Modular and lightweight structures with integrated foam insulation are increasingly being used replacing traditional building concepts.
For economic and societal sustainability reasons, companies must design packaging so that it uses just enough material to ensure that the foods and goods they contain survive the distribution chain and are delivered to consumers in the best possible condition. Polymer foams support these material reduction needs while maintaining required packaging property profiles.
Taking weight out of a car is important in reducing fuel consumption. Low noise and high comfort are important for occupant convenience when travelling. Foamed solutions can meet these key requirements and offer additional functionality.
SABIC puts the polymer foam value chain into sharp focus
SABIC is increasing its focus on key market segments. This focus is part of a transformation program to accelerate implementation of its corporate 2025 strategy to become the world preferred supplier in the chemical industry. SABIC has identified “foaming and lightweight” as an important focus area, where its numerous polymer-based solutions can help the entire value chain become more efficient, more sustainable and more profitable.
SABIC‘s diverse product portfolio reflects its customer-driven focus and its commitment to developing innovative and high-quality foam solutions that are designed to last. SABIC is committed to the development of innovative solutions that go beyond its already established foam solutions portfolio.
SABIC’s intensified focus on forms will cover not only the converters but the entire value chain. It has put in place dedicated business, marketing and sales teams, together with technical and compliance experts, to offer insights on customised applications and solutions with the most added value. This new set-up will enable a more focused and faster implementation of solutions to meet the needs of customers and partners around the world.
How does SABIC focus on foam technology?
With over 35 years of experience in foams, SABIC has a significant share of the market for foamable polyolefins, thanks in large part to its ability and willingness to tailor grades for the specific needs of the market. These grades are already made in Europe and now also in Saudi Arabia, enabling SABIC to supply customers all around the world. SABIC also supplies polystyrenefoam solutions into the Middle East and Africa (MEA) market from its operations in Saudi Arabia.
SABIC already has an extensive and growing network involving partners from machine suppliers, foam producers and converters, additive suppliers, institutes and universities, and other parties actively involved in the foam production and conversion chain. This has put SABIC in a strong position to understand the foam market, its needs and drivers.
SABIC has recently redrawn its roadmap for foams to encompass the following:
  • Expansion of its current portfolio beyond polyethene and polystyrene to include more polyolefins, such as polypropylene, polyolefin elastomers (POEs) and polyolefin elastomers (POPs), and engineering thermoplastics;
  • Collaboration through the value chain to generate a fullest possible set of solutions for polymer foams;
  • Dedicating a Global Innovation Center to Foam & Lightweight;
  • Leveraging its European market position globally.
Extending the possibilities in polyolefins
Polyolefin elastomers (POPs) and polyolefin elastomers (POEs) are important additions to SABIC’s portfolio of foam solutions. The biggest outlet for these polymers is currently as additives in other solid polymers, where they improve properties such as impact resistance. They can also be used in foam grades to enable the production of foams that are more flexible and resilient, especially at low temperatures. SABIC is currently developing POP and POE grades for use in foams.
Beyond polyolefins and foam extrusion
SABIC is very strong in polyolefins for extruded foams, where use is often made of their flexibility. But more rigid applications normally require the use of different process technologies, such as injection moulding and blow moulding. SABIC is developing foaming solutions for these processes as well, catering for latest down-gauging and lightweight trends that are most evident in the automotive industry. Here, solid plastics have already replaced metals in many applications, and now foamed solutions are further reducing the weight of automotive products. SABIC intends to take a leading role in future collaboration with partners to advance the use of foaming technologies in part moulding.
Many machinery suppliers already offer special physical foaming equipment for production of cellular injection moulded and blow moulded parts. But optimum solutions come through matching process technologies with tailor- made resin recipes. SABIC is looking into new lightweight solutions and modifying resins to make them more suitable for these “hybrid” processes.
SABIC also has foamable grades of such engineering plastics as polycarbonate, modified PPE (NORYLTM) and TM PEI (ULTEM ), for high-end applications in such areas as aviation as well as in various areas inland transport. These materials make possible such products as sandwich panels with foam cores that combine very high strength with low weight, as well as enhance flame retardance. LEXANTM FLIGHT F6L300 thermoformable sheet, for example, is 40% lighter than a traditional solid sheet.
Meeting value chain needs through state-of-the-art solutions
Close collaboration with customers has enabled SABIC to build up a large bank of knowledge on the various foaming processes and to develop dedicated grades that better meet customer needs. Now, SABIC is creating new state-of-the-art solutions that will enable producers and converters to make better forms and foamed products, even more, cost effectively. Several breakthrough innovations are in the process of being commercialised. The first fruits of this more focused approach are already visible in several newly developed polyolefin grades.
SABIC LDPE 2502X0, for example, offers special benefits for the physical foam extrusion process, as well for the resulting lightweight foams. The material is less sensitive to web breaks and foam collapse compared to current materials, resulting in a higher material yield during processing. The SABIC foams produced have a higher compression strength and better resilience, as well as lower foam density, compared to similar materials.
SABIC LDPE 2402CX0 offers benefits for cross-linkable (XL) foam extrusion processes, and the corresponding crosslinked lightweight foams. This material shows a unique controlled reactivity combined with outstanding consistency, resulting in very stable processing with higher material yields. The XL foams have an improved properties-to-weight ratio, offering the possibility to use them in higher added-value applications.
More innovations ahead
SABIC is also developing technologies to increase productivity at foam producing customers. Extruded foams currently have to be held in storage, sometimes for as long as ten days, after production in order for them to stabilise as the blowing agent escapes from the foam cells and is replaced by air. Only then can they be cut and laminated for further conversion. SABIC now has a breakthrough solution, already validated with key customers, that enables the foams to stabilise in just a few days. This will provide a considerable saving in time to market and is likely to free up large areas of storage space at producers and increase storage efficiency.
This advance is aimed mainly at the packaging foam market but is applicable as well to foams produced for various applications in different markets. This is particularly important since SABIC foam producing customers are generally supplying to multiple industries.
Further innovations in polymer foams are already being planned and executed at SABIC’s new Foam Innovation Center in the Netherlands. This Center is equipped with most foam process capabilities as well as analytical equipment, enabling SABIC to carry out developments on new foam solutions, technology innovations and collaborative projects with customers, to reduce the material footprint, enable energy and cost reductions, and decrease time to market.
In SABIC’s Home of Innovation in Saudi Arabia, SABIC is already showcasing the latest solutions for its polymer and foam solutions. It continues to push the boundaries of technology to discover even better, more sustainable energy-saving solutions.
With its emphasis on innovation and its extensive experience and expertise in development and production of numerous types of thermoplastics for foams used across many sectors, SABIC sees itself as a strong partner that can be relied upon to provide advanced, high quality, sustainable solutions for its customers – and to open the door to new possibilities.
Author: Frank de Vries is Global Director, Foam & Lightweight at SABIC. 
© Chemical Today Magazine
Read More: Foam innovations addressing global challenges

Reliance inaugurates world-class research centre in India

VADODARA, INDIA: Reliance Industries Ltd (RIL) inaugurated its technologically advanced product application & research centre (PARC) at Vadodara, India. The PARC will focus on creating value addition opportunities, not only for RIL’s polymer business but also for its customers by offering technical, product upgradations and application development services.
The PARC initially set up in Mumbai in 1990 with the sole objective of providing product support solutions to customers, has now been transformed into a crucial R&D facility for polymers, such as polypropylene (PP), polyethylene (PE) and polyvinyl chloride (PVC).
The PARC houses the best brains of polymer technology, engineering and sector specialities. The team works tirelessly, creating opportunities and providing solutions to the ever-growing market needs and customer demands. The team is equipped with providing best-quality technical services, benchmarking, development of new grades in polymers, and inventions of applications.
The processing machinery section at PARC is equipped with advanced machinery that can use PE for making mono & multilayer blown films, PP TQ film, PE & PP cast films & sheets. The huge shop floor also equipped to make articles through the processes of blow moulding, injection moulding, roto-molding, compression moulding and pipe extrusion.
The PARC team also engages with end-user industries, such as FMCG, automobile, food and beverages, agriculture, OEMs converters and other polymer processors.
The applications laboratory at the PARC, one of the best in India, is capable of performing tests for characterization of polymers in accordance with the Indian and international standards. It is equipped with facilities for physical, mechanical, thermal, optical, environmental and rheological tests.
The PARC offers its processing and testing services to customers – value-added services like an evaluation of their existing products, formulation of new products, a creation of new applications and helping them meet the global standards.
It is imperative to mention here that the PARC’s biggest achievement is the development and introduction of Octene LLDPE film grade for milk packaging, and plastic weaved sack for food grain packaging. They have benefited the public at large by enhancing shelf life and reducing wastage of milk, food grains and vegetables. 
The PARC is also spearheading training programs for plastic processors, converters, operators and young polymer professionals, thus contributing towards knowledge enhancement of the polymer fraternity.
Further, the PARC team actively engages with polymer-centric education institutions, industry associations and machinery manufacturers for the development of the industry and knowledge sharing.
“The PARC at Vadodara possesses a spacious shop floor and state-of-the-art labs that are equipped with the world’s finest processing and testing equipment. It has been tailored to cater to the ever-growing needs and expectations of our customers. I believe that a facility of this magnitude will go a long way to ensure that Reliance is at the quality frontier of our industry, globally,” said Ajay Shah, president - polymer chain, RIL.
© Worldofchemicals News
Read More: Reliance inaugurates world-class research centre in India